Reactions of tetrasulphur tetranitride with halides. Part IV. The formation of cyclopentathiazenium salts in thionyl chloride
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 23,p. 2658-2661
- https://doi.org/10.1039/dt9720002658
Abstract
Tetrasulphur tetranitride reacts with thionyl chloride in the presence of ferric or aluminium chloride to give a mixture of the tetrachlorometallates (MCl4 –, M = Fe or Al) of the cations S3N2Cl+, S4N3 +, and the new species S5N5 +; their i.r. spectra are discussed. These three cations appear to be members of a potentially large class of inorganic aromatic SN species.Keywords
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