Palladium-Catalyzed Asymmetric Alkylation of 2,3-Alkadienyl Phosphates. Synthesis of Optically Active 2-(2,3-Alkadienyl)malonates
- 1 February 2002
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 31 (2) , 140-141
- https://doi.org/10.1246/cl.2002.140
Abstract
Asymmetric alkylation of 2,3-alkadienyl phosphates with soft carbon nucleophiles proceeds efficiently in the presence of palladium complex catalyst bearing MeOBIPHEP or BINAP ligand to give optically active functionalized allenes up to 90% ee.Keywords
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