Die isomeren 3.5‐Di‐tert.‐butyl‐cyclohexanole Solvolysegeschwindigkeiten ihrer Toluolsulfonate
- 22 February 1965
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 682 (1) , 75-89
- https://doi.org/10.1002/jlac.19656820108
Abstract
Die isomeren 3.5‐Di‐tert.‐butyl‐cyclohexanole A, B und C werden in reiner Form dargestellt und in ihrer Konfiguration zugeordnet. Das trans‐cis‐3.5‐Di‐tert.‐butyl‐cyclohexanol (B) liegt überwiegend in der twist‐Konformation vor. Im Vergleich zu den Tosylaten des all‐cis‐ und des trans‐trans‐Isomeren zeigt sein Tosylat bei der Äthanolyse und Acetolyse eine stark erhöhte Reaktionsgeschwindigkeit.Keywords
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