Detection of reactive rhodium containing intermediates following flash photolysis of a tris(β-diketonato)rhodium(III) complex

Abstract
Flash photolysis of trans-tris(1,1,1-trifluoropentane-2,4-dionato)rhodium(III) in alcoholic solvents produces a short-lived RhII-containing species which decays to a longer-lived intermediate tentatively identified as a RhII-hydride.

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