Catalytic, Asymmetric Synthesis of the C1‘−C10‘ Segment of Pamamycin 621A
- 29 April 2000
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (11) , 1529-1531
- https://doi.org/10.1021/ol005714t
Abstract
[reaction--see text] This paper describes a catalytic, asymmetric approach to the C(1)(')-C(10)(') segment of pamamycin 621A. We synthesize this segment in a convergent manner, with each of the coupling partners ultimately deriving from enantiomerically enriched methylketene dimer.Keywords
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