Fast molecular dynamics: Novel effects studied by 3 cm and 2 mm band EPR
- 1 January 1992
- journal article
- Published by Walter de Gruyter GmbH
- Vol. 64 (6) , 873-881
- https://doi.org/10.1351/pac199264060873
Abstract
1: Abstract - Motional characteristics were calculated for new type or free radicals starting from the anisotropic parameters obtained with the high resolution 2 mm band EPR. The general approach for derivinp; parameters of molecular tumbling and chemical exchange in the same experiment is discussed. A rather strong correlation between molecular and chemical dynamics of free radicals has been observed.Keywords
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