Unexpected P−Si or P−C Bond Cleavage in the Reaction of Li2[(C5Me4)SiMe2PR] (R = Cyclohexyl, 2,4,6-Me3C6H2) and Li[(C5H4)CMe2PHR] (R = Ph, tBu) with ZrCl4 or [TiCl3(thf)3]: Formation and Molecular Structure of the ansa-Metallocenes [{(η-C5Me4)2SiMe2}ZrCl2] and [{(η-C5H4)2CMe2}MCl2] (M = Ti, Zr)†
- 31 May 2000
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 19 (13) , 2556-2563
- https://doi.org/10.1021/om990763z
Abstract
No abstract availableKeywords
This publication has 35 references indexed in Scilit:
- Internally Phosphine-Stabilized Zirconocene Cations Employing Substituted ((Diarylphosphino)methyl)cyclopentadienyl Ligand SystemsOrganometallics, 1997
- Synthesis and Crystal Structure of Some Novel Titanocene Phosphido Compounds by P−H Activation in the Presence of HydrosilanesJournal of the American Chemical Society, 1997
- SYNTHESIS AND MOLECULAR STRUCTURE OF Mes(H)P-P(H)Mes (Mes = 2,4,6-Me3C6H2)Phosphorus, Sulfur, and Silicon and the Related Elements, 1996
- Hochmolekulares Polypropylen durch maßgeschneiderte ZirconocenkatalysatorenAngewandte Chemie, 1992
- Mono‐, Bis‐ and Tris(cyclopentadienyl) Compounds ‐ Syntheses of New Polydentate Ligands and their Molybdenum and Tungsten ComplexesEuropean Journal of Inorganic Chemistry, 1991
- Erstes Beispiel eines ethylenselektiven löslichen Ziegler‐Katalysators der Zirconocen‐KlasseAngewandte Chemie, 1989
- The organic chemistry of phospholesChemical Reviews, 1988
- Synthesis, structural characterization, and electrochemistry of [1]metallocenophane complexes, [Si(alkyl)2(C5H4)2]MCl2, M = Ti, ZrInorganic Chemistry, 1985
- Polymerisation von Propen und Buten mit einem chiralen Zirconocen und Methylaluminoxan als CokatalysatorAngewandte Chemie, 1985
- The molecular and crystal structure of (PC6H11)4Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1969