The utility of (C5Me5)2Sm in isolating crystallographically characterizable zintl ions. X-Ray crystal structure of a complex of (Sb3)3?
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1138-1139
- https://doi.org/10.1039/c39920001138
Abstract
(C5Me5)2Sm reacts with Sb(Bun)3 in toluene to from [(C5Me5)2Sm]3(µ-η2:η2:η1-Sb3)(thf)(thf = tetrahydrofuran), which contains a bent (Sb3)3– ion [114.5(1)°] with an average Sb–Sb distance of 2.688(1)Å.Keywords
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