Spin Densities in Azo-Type Radical Anions
- 15 March 1965
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 42 (6) , 2033-2037
- https://doi.org/10.1063/1.1696242
Abstract
Various methods of calculating 14N hyperfine splittings are compared with the experimental splitting constants observed for benzo[c]cinnoline, trans-azobenzene, and 1,4-dimethyltetrazine radical anions in dimethyl sulfozide [80%]—t-butyl alcohol [20%] solution. The theory of Stone and Maki gives reasonable results although better argument is obtained by use of a modified value for QCNN of 13.8 G.Keywords
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