Unexpected inversion of configuration at a quaternary centre during the acetolysis ofD-homo-5α-androstan-17aβ-yl tosylate
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 341
- https://doi.org/10.1039/c39730000341
Abstract
Acetolysis of D-homo-5α-androstan-17aβ-yl tosylate (I) gave the 17aβ-yl acetate (II) accompanied by D-homo-5α,13α-androstan-17aα-yl acetate (III), resulting from inversion of configuration at the quaternary centre adjacent to the reaction site.Keywords
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