Molecular structure of bis(trifluoromethyl)hydroxylamine : an electron diffraction study
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16,p. 1735-1737
- https://doi.org/10.1039/dt9720001735
Abstract
The molecular structure of bis(trifluoromethyl)hydroxylamine, (CF3)2NOH, has been determined in the vapour phase by the sector microphotometer electron diffraction method. Principal structural parameters with estimated standard deviations in parentheses are: r(N–O) 1·40(3), r(C–N) 1·435(fixed), and r(C–F) 1·322(2)Å; F–C–F 109·8(0·4), C–N–C 120·6(1·3), C–N–O 111·3°(0·8°). The longer N–O bond and smaller sum of angles at nitrogen than in (CF3)2NO result in rather similar FO distances in the two molecules.Keywords
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