Investigations on sterols XXI: An alternative route for the synthesis of some 6‐dehydro‐9β,10α‐steroid hormone analogues
- 1 January 1963
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 82 (11) , 1107-1114
- https://doi.org/10.1002/recl.19630821115
Abstract
Selective ozonisation of isolumisterone produced 9β,10α‐bisnorchola‐4,6‐dien‐3‐on‐22‐al. This compound could be converted into: 6‐dehydro‐9β,10α‐progesterone (9β,10α‐pregna‐4,6‐diene‐3,20‐dione); 6‐dehydro‐17α‐hydroxy‐9β,10α‐progesterone (9β,10α‐pregna‐4,6‐dien‐17α‐ol‐3,20‐dione) and 6‐dehydro‐9β,10α‐testosterone (9β,10α‐androsta‐4,6‐dien‐17β‐ol‐3‐one).Keywords
This publication has 3 references indexed in Scilit:
- Investigations on sterols XIX: 6‐Dehydro‐9β, 10α‐progesterone from pregnenoloneRecueil des Travaux Chimiques des Pays-Bas, 1961
- Investigations on sterols XV: The syntheses and properties of 9β,10α‐progesterone and 6‐dehydro‐9β,10α‐progesteroneRecueil des Travaux Chimiques des Pays-Bas, 1960
- 500. Partial reduction of steroid hormones and related substances. Part III. The reaction of αβ-unsaturated ketones with zinc in acetic acidJournal of the Chemical Society, 1959