A Theory of Chemical Separations: Thermodynamic Relationships in Linear Multistate Chemical Systems

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Abstract
A simple relationship between the over-all thermodynamic equilibrium constant and the thermodynamic equilibrium constants for the individual partition states that occur within a linear multistate chemical system is derived. The interrelationships between the various parameters that characterize gas-liquid systems—the symmetrical activity coefficient at infinite dilution, Henry's constant, and the partition coefficient—are treated in detail to demonstrate the application of the theoretical results.