The Glycosyltransferase Gene Encoding the Enzyme Catalyzing the First Step of Mycothiol Biosynthesis ( mshA )

Abstract
Mycothiol is the major thiol present in most actinomycetes and is produced from the pseudodisaccharide 1 d - myo -inosityl 2-acetamido-2-deoxy-α- d -glucopyranoside (GlcNAc-Ins). A transposon mutant of Mycobacterium smegmatis shown to be GlcNAc-Ins and mycothiol deficient was sequenced to identify a putative glycosyltransferase gene designated mshA . The ortholog in Mycobacterium tuberculosis , Rv0486, was used to complement the mutant phenotype.

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