Pseudo-sugars. 5. Synthesis of Dl-Validatol and Dl-Deoxyvalidatol, and Their Epimers

Abstract
New cyclitols, validatol and deoxyvalidatol, derived by hydrogenolysis of antibiotic validamycin A, were synthesized as the racemates from readily available tri-O-acetyl-(1,3/2,4,6)-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol.

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