Palladium(0)-Catalyzed Cyclization-Carbonylation of 2,7-Octadienyl Acetate and Analogs
- 1 June 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (6) , 955-958
- https://doi.org/10.1246/cl.1989.955
Abstract
The palladium(0)-catalyzed carbonylation of 2,7-octadienyl acetate and analogs via π-allylic intermediates can be preceded by their intramolecular olefin insertion, in acetic acid, affording 2-vinylcyclopentylacetic acid and derivatives therefrom.Keywords
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