Application of Ion-Exclusion Chromatography to the Study of Equilibria of Anionic Complexes
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 13 (16) , 1441-1449
- https://doi.org/10.1080/00032718008081380
Abstract
An ion-exclusion chromatographic method for the determination of a stability constant of an anionic metal complex has been devised. The stability constants (1og β1) of magnesium diphosphate and magnesium triphosphate complexes at 1=0.1 and 15°C were evaluated to be 5.06 and 5.89 in sodium chloride solution.Keywords
This publication has 10 references indexed in Scilit:
- Application of Gel Chromatography to the Determination of the Stability Constants of a Magnesium Complex with DiphosphateBulletin of the Chemical Society of Japan, 1978
- Determining the stability constant of a metal complex by gel chromatographyJournal of Chemical Education, 1977
- Gel and ion-exchange chromatographic purification of the reaction products between diphosphate and diphosphonateJournal of Chromatography A, 1977
- The Relationship Between the Retention Time of a Metal and the Free Ligand Concentration of an Eluent in Gel ChromatographyAnalytical Letters, 1977
- Determination by gel filtration of association constants for metal-nucleotide interactionAnalytical Biochemistry, 1972
- The application of gel filtration to the study of protein-binding of small moleculesChromatographic Reviews, 1970
- Interaction of Copper(II) with Deoxyribonucleic Acid below 30°*Biochemistry, 1967
- The complexometric analysis of pyro- and triphosphates—I: Stability constants of the proton and metal complexes of the acidsTalanta, 1963
- Measurement of protein-binding phenomena by gel filtrationBiochimica et Biophysica Acta, 1962
- A new reagent for the colorimetric and spectrophotometric determination of phosphorus, arsenic and germaniumAnalytica Chimica Acta, 1957