Notizen/Notes. Natrium‐ und Kaliumfluorsilylamide – Synthese und Kristallstruktur
- 1 May 1990
- journal article
- research article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 123 (5) , 1039-1041
- https://doi.org/10.1002/cber.19901230516
Abstract
Sodium and Potassium Fluorosilylamides – Synthesis and Crystal Structurestert‐Butyl(di‐tert‐butylfluorosilyl)amine (1) reacts with sodium or potassium to give the alkali salts 2 or 3, respectively. 2 and 3 crystallize as THF adducts and form head‐to‐tail dimers. Sodium is tetracoordinated in 2 and potassium hexacoordinated in 3. The crystal structures of the alkali salts are discussed.Keywords
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