Investigation of strained transition states in free radical copolymerizations by means of high-pressure kinetics
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 851-852
- https://doi.org/10.1039/c39790000851
Abstract
Increasing substitution of the comonomer in high-pressure, free-radical copolymerizations of maleic anhydride with multisubstituted olefins involves greater pressure acceleration and hence more negative activation volumes and later transition states.Keywords
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