The first complexes of cyanogen halides with silver(I): crystal structure of [Ag(NCCl)2][SbF6]
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 2507-2508
- https://doi.org/10.1039/dt9880002507
Abstract
The reactions of Ag[AsF6] or Ag[SbF6] with ClCN, BrCN, and ICN yield the complexes [Ag(NCCl)2][AsF6], [Ag(NCCl)2][SbF6], [Ag(NCBr)2][AsF6], [Ag(NCBr)2][SbF6], and [Ag(NCl)2][AsF6]. The salt [Ag(NCCl)2][SbF6] was characterized by an X-ray single-crystal structure investigation. The cation is monomeric. The cyanogen halide is bonded to the silver through nitrogen, with Ag–N 2.140(4)Å. The co-ordination geometry at silver is exactly linear.Keywords
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