Intramolecular vibrational energy flow induced by potential and Coriolis couplings
- 15 March 1989
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 90 (6) , 3159-3170
- https://doi.org/10.1063/1.455866
Abstract
The classical dynamics of intramolecular energy flow caused by potential and Coriolis couplings is studied in various representations. The mapping of the problem onto a perturbed asymmetric rotor is found particularly useful. This representation shows the origin of localization/delocalization of energy as well as factors that determine periodic energy exchange. Good agreement is found between the predictions and numerical calculations.Keywords
This publication has 43 references indexed in Scilit:
- Systematic corrections to the rotating-wave approximation and quantum chaosPhysical Review A, 1987
- Lie algebraic approach to quantization of nonseparable systems with internal nonlinear resonanceThe Journal of Chemical Physics, 1986
- Anharmonic local-mode-normal-mode transformations: an algebraic treatmentThe Journal of Physical Chemistry, 1986
- Patterns of energy levels and spectra for polyatomic moleculesJournal of Statistical Physics, 1984
- Rotational energy surfaces and high-J eigenvalue structure of polyatomic moleculesThe Journal of Chemical Physics, 1984
- Field-induced barrier penetration in the quartic potentialPhysical Review A, 1984
- Stochastic instability of a nonlinear oscillatorPhysical Review A, 1979
- STOCHASTIC INSTABILITY OF NON-LINEAR OSCILLATIONSSoviet Physics Uspekhi, 1972
- Free Rotation of a Rigid Body Studied in the Phase PlaneAmerican Journal of Physics, 1967
- Zur Quantelung des asymmetrischen Kreisels. IIThe European Physical Journal A, 1929