The stereochemistry of melianone and sapelin F: correlation with bourjotinolone A
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 517-518
- https://doi.org/10.1039/c39750000517
Abstract
Thermolysis of the epoxytriol (9) from melianone (4) gave 3-episapelin A (2), thus defining the stereochemistry of melianone (4) as 23-R,24-S; sapelin F (16) is shown also to have 23-R,24-S stereochemistry by correlation with melianone via 3-epimeliantriol (13).Keywords
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