Influence of Fermi Resonance on the Centrifugal Stretching Constant of a Linear Molecule
- 1 January 1956
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 24 (1) , 44-47
- https://doi.org/10.1063/1.1700851
Abstract
A theory of the influence of Fermi resonance on the centrifugal distortion constant of a linear molecule has been developed and its predictions for CO2 compared with experiment. The theory of those bands which exhibit simultaneous Fermi resonance and l‐type doubling is also discussed.Keywords
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