CuIIcomplexation by a tritopic macrocyclic ligand. A doubly µ3-hydroxo bridged trinuclear copper(II) cryptate
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 74-76
- https://doi.org/10.1039/c39850000074
Abstract
The tritopic hexa-aza-macrocycle (1) binds three CuII ions in solution and leads in particular to the assembly of a trinuclear bis-µ3-hydroxo bridged complex whose crystal structure has been determined; it may be considered as a cryptate of a cationic cluster [Cu3(OH)2]4+ held inside the macrocyclic cavity of the ligand.Keywords
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