The chemistry of copper(I) complexes. Part II. Halogeno-complexes containing triphenyl-arsine or -stibine
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2444-2446
- https://doi.org/10.1039/j19710002444
Abstract
Complexes having ligand to metal ratios of 1:1, 3:2, 2:1, and 3:1 have been isolated from the reactions of copper(II) halides (or Cul) and triphenyl-arsine or -stibine. The ligands are very labile in solution, and are completely displaced by an excess of bidentate ligand. Under controlled conditions both mono- and bi-dentate ligands yield CuX(MPh3)L derivatives.Keywords
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