Stereoselective Synthesis of Unsaturated Polyhydroxylated Amino Acids via Ester Enolate Claisen Rearrangement

1 October 1996

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1996 (10) , 975-977
https://doi.org/10.1055/s-1996-5637

Abstract

Ester enolate Claisen rearrangement of chelated N-protected chiral allylic amino acid esters results in the formation of polyhydroxylated γ,δ-unsaturated amino acids in good yields and with a high degree of chirality transfer.

Keywords

CHELATED ENOLATE
CLAISEN REARRANGEMENT
POLYHYDROXYLATED AMINO ACIDS
Α-ALKYLATED AMINO ACIDS

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