The X-ray crystal structure of a ternary cocrystallization compound: N,N-dimethyl-o-phenylenediamine–fluoroboric acid–triphenylphosphine oxide
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1694-1695
- https://doi.org/10.1039/c39910001694
Abstract
The endo-bidentate chelated structure of the title compound corresponds to protonation on the dimethylamino group; the oxygen atom of triphenylphosphine oxide acts as a double acceptor of hydrogen bonds.Keywords
This publication has 10 references indexed in Scilit:
- Hydrogen bond directed cocrystallization and molecular recognition properties of acyclic imidesJournal of the American Chemical Society, 1991
- Hydrogen bond-directed cocrystallization and molecular recognition properties of diarylureasJournal of the American Chemical Society, 1990
- Chemical bonding in hypervalent molecules. The dominance of ionic bonding and negative hyperconjugation over d-orbital participationJournal of the American Chemical Society, 1990
- Triphenylphosphine oxide as a crystallization aidJournal of the American Chemical Society, 1988
- Rational synthesis of metalla–sulphur–nitrogen complexes: use of [Me2SnS2N2]2 in the preparation of complexes of the type [M(S2N2H)(PR3)2]X(M = Pt or Pd). X-Ray structures of [Pt(S2N2H)(PEt3)2][Me2SnCl3],[Pt(S2N2H)(PBun3)2]2[PF6]Cl, and [{Co(S2N2H)2}2{Ph2P(O)CH2CH2P(O)Ph2}]J. Chem. Soc., Dalton Trans., 1987
- Crystal Structure of the Hydrogen-bonded Complex between Pentafluorophenol and Triphenylphosphine Oxide.Acta Chemica Scandinavica, 1986
- Lone-pair directionality in hydrogen-bond potential functions for molecular mechanics calculations: the inhibition of human carbonic anhydrase II by sulfonamidesJournal of the American Chemical Society, 1985
- Hydrogen-bond geometry in organic crystalsAccounts of Chemical Research, 1984
- Directional hydrogen bonding to sp2- and sp3-hybridized oxygen atoms and its relevance to ligand-macromolecule interactionsJournal of the American Chemical Society, 1984
- Systematic analysis of structural data as a research technique in organic chemistryAccounts of Chemical Research, 1983