Studies of silver electronucleation onto carbon microelectrodes
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 90 (13) , 1923-1929
- https://doi.org/10.1039/ft9949001923
Abstract
It is shown that it is possible to use microelectrodes to develop a number of strategies for the measurement of silver electronucleation kinetics at the molecular level. The direct measurement of individual events and therefore stochastic deterministic growth of the centres allows determination of an accurate value of the arrival time of the first nucleus. The distribution of these arrival times follows the simplest model of a pure birth process with identical rate constants for all the aggregation steps.Keywords
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