First synthesis of soluble, well defined coordination polymers from kinetically unstable copper(I) complexes

1 January 1996

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 23,p. 2639-2640
https://doi.org/10.1039/cc9960002639

Abstract

Exclusion of competitive ligands is found to be the central requirement for obtaining solutions of constitutionally homogeneous, high-molecular-mass coordination polymers from kinetically unstable pseudo-tetrahedral complexes of copper(I) and o-phenanthroline derivatives.

Keywords

COPPER
PSEUDO
CONSTITUTIONALLY
PHENANTHROLINE
HOMOGENEOUS
TETRAHEDRAL
SOLUBLE
COMPETITIVE
COORDINATION POLYMERS

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