Deoxovanadium(IV) complexes of the dibenzotetramethyltetra-aza[14]-annulene ligand: formation of products containing thioxo-, µ-nitrido-, and oxidatively coupled ligands
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 910-911
- https://doi.org/10.1039/c39810000910
Abstract
Deoxygenation of the oxovanadium(IV) complex, V(C22H22N4)O, with anhydrous HCl yields V(C22H22-N4)Cl2˙HCl from which a thioxo-complex, V(C22H22N4)S, is obtained by reaction with H2S, and a µ-nitrido-complex [V(C22H22N4)–N–V(C22H22N4)]+ is obtained by reaction with ammonia; a ligand-coupled dimer of V(C22H22N4)O is obtained by reaction with mild oxidants.Keywords
This publication has 0 references indexed in Scilit: