Phase diagrams of ‘‘simple’’ fluids with extreme pair potentials
- 1 August 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 73 (5) , 752-755
- https://doi.org/10.1103/physrevlett.73.752
Abstract
It is shown that strongly reducing the range of the attractions of a simple fluid will transform its phase diagram from the usual type, with a fluid-fluid critical point and a fluid-fluid-solid triple point, into its fluid-solid mirror image, with a solid-solid critical point and a solid-solid-fluid triple point. This scenario could be of relevance to the phase behavior of colloidal dispersions.Keywords
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