Identification of L-nitrosuccinate as an intermediate in the fungal biosynthesis of 3-nitropropanoic acid
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 757-758
- https://doi.org/10.1039/c39880000757
Abstract
D,L-Diethyl [15N]nitrosuccinate is efficiently incorporated into 3-nitropropanoic acid (1) by cells of Penicillium atrovenetum; incorporation of L-[2,3,3-2H3]aspartate into (1) with retention of the C-2 deuterium of the amino acid allows assignment of the chirality of the intermediate.Keywords
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