Unstable intermediates. Part CXXXV. The formation of Sn3+ and Pb3+ centres in irradiated tin and lead salts, and their electron spin resonance parameters
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 21,p. 2233-2236
- https://doi.org/10.1039/dt9730002233
Abstract
A wide range of stannous, stannic, plumbous, and plumbic compounds have been exposed to 60Co γ-rays at 77 K and their e.s.r. spectra studied. In most cases very high-field features were detected that can be ascribed to species containing 119Sn, 117Sn, and 200Pb nuclei. These are thought to be Sn3+ and Pb3+ ions bonded to various ligands characteristic of the host lattices. Trends in the derived hyperfine coupling constants are discussed in terms of environmental effects.Keywords
This publication has 0 references indexed in Scilit: