X-Ray crystal structure of (tetraphenylimidodiphosphinato)silver(I): an unexpected tetranuclear complex with two modes of coordination of silver
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2299-2300
- https://doi.org/10.1039/a706430f
Abstract
Potassium tetraphenylimidodiphosphinate reacts with silver nitrate to give, upon recrystallization from ethanol, an unexpected tetranuclear complex [Ag{N(OPPh2)2}]4·2EtOH, the structure of which is established by X-ray crystallography; preliminary results concerning its use as a catalyst for the aerobic co-oxidation of alkenes and aldehydes are described.Keywords
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