External vs. internal cyclopropyl bond cleavage in the photosensitized epimerization of bicyclo[3,1,0]hex-2-enes

Abstract
The photosensitized epimerizations of bicyclo-[3,1,0]hex-2-ene-6-endo-carboxylic acid and its methyl ester occur exclusively by cleavage of the external cyclopropyl bond.

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