New bis(ethylenedithio)tetrathiafulvalene derivatives with low oxidation potentials

Abstract
The efficient synthesis of three new vinylogous derivatives 6–8 of bis(ethylenedithio)tetrathiafulvalene (BEDT–TTF) is described; cyclic voltammetry establishes that the new donors have significantly lower solution oxidation potentials than that of BEDT–TTF, and the single crystal X-ray structure of compound 8 is described.

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