Specific heat ofand-mixtures at theirtransition
- 1 July 1975
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 12 (1) , 93-113
- https://doi.org/10.1103/physrevb.12.93
Abstract
We have measured the specific heat near the transition of pure and of five - mixtures up to a mole fraction of 0.39 in . Our data for confirm the results of Ahlers revealing an asymmetry in the exponents above and below when the specific heat is represented by a simple-power-law temperature dependence. Our results for these exponents ( and ) differ somewhat from Ahlers's. Our results can be reconciled with the requirement of scaling () only by supposing substantial contributions to are made by singular correction terms to a simple power law. The measured specific heat of the mixtures richest in appears to be finite, continuous, and cusped at the line. These qualitative features have been termed "renormalization" by Fisher. An analysis of our mixture data with a power-law temperature dependence does not yield a fully renormalized exponent, but rather an effective exponent. We have calculated the following derivatives at the line: , , and . We have used these derivatives to calculate the specific heat along paths of constant pressure and constant relative chemical potential . This specific heat behaves very much like of pure supporting the idea of universality for the specific-heat exponents. It is also true that the same asymmetry in the branches above and below which is observed in pure is retained in the mixtures. The persistence of the asymmetry of
Keywords
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