Reaction of a silyl–copper reagent with acetylenes: a new synthesis of vinylsilanes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 276-277
- https://doi.org/10.1039/c39800000276
Abstract
A silyl-cuprate reagent adds regioselectively to terminal acetylenes and the intermediate (3) reacts with electrophiles to give 2,2-disubstituted vinylsilanes.Keywords
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