An Extended Flame Zone in the Combustion of CH3Cl
- 1 January 1995
- journal article
- research article
- Published by Taylor & Francis in Combustion Science and Technology
- Vol. 106 (4-6) , 229-238
- https://doi.org/10.1080/00102209508907780
Abstract
Three laser-based techniques have been used for the measurement of relative concentration profiles of the radicals Cl, CH2Cl, and CH3 and several major species in a low pressure, premixed, laminar CH4/CH3Cl/O2/Ar flame. The chlorine atom concentration is suppressed throughout the primary flame zone associated with the production of H, O, and OH radicals, but increases rapidly, by the reconversion of HCl to Cl, within an extended flame zone.Keywords
This publication has 24 references indexed in Scilit:
- Laser-based flame species profile measurements: A comparison with flame model predictionsCombustion and Flame, 1993
- Laser-driven electron ionization for a VUV photoionization time-of-flight mass spectrometerReview of Scientific Instruments, 1991
- A computational study of chlorine inhibition of CO flamesCombustion and Flame, 1987
- Resonantly enhanced two-photon spectroscopy of HCl and DCl in the 77 000–87 000 cm−1 regionThe Journal of Chemical Physics, 1987
- Molecular beam mass spectroscopic study of trichloroethylene flamesEnvironmental Science & Technology, 1986
- Detection of Cl atoms and HCl molecules by resonantly enhanced multiphoton ionizationChemical Physics Letters, 1985
- A Computational Study of the Inhibition of Humid CO Oxidation by HCI and CI2 during the Induction PeriodCombustion Science and Technology, 1985
- On the Combustion of Chlorinated Hydrocarbons I. TrichloroethyleneCombustion Science and Technology, 1983
- Molecular beam mass spectrometry for studying the fundamental chemistry of flamesProgress in Energy and Combustion Science, 1977
- Molecular beam mass spectrometry applied to determining the kinetics of reactions in flames. I. Empirical characterization of flame perturbation by molecular beam sampling probesCombustion and Flame, 1974