The first crystal and molecular structure of lanthanide homodinuclear macrocyclic complexes showing metal–metal pair interactions
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1531-1533
- https://doi.org/10.1039/c39890001531
Abstract
Template condensation of 2,6-diformyl-p-cresol with 3,6-dioxa-1,8-octanediamine in the presence of lanthanide nitrates, yields homodinuclear macrocyclic complexes; solution of the structure of the gadolinium complex confirms encapsulation of a lanthanide cation pair in the macrocycle and luminescence of Eu3+ indicates Eu–Eu interactions.Keywords
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