THE REACTIONS OF ACTIVE NITROGEN WITH HYDROGEN SULPHIDE AND CARBON DISULPHIDE
- 1 March 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (3) , 334-342
- https://doi.org/10.1139/v60-049
Abstract
The destruction of either hydrogen sulphide or carbon disulphide by active nitrogen appears to be minimal at some temperature in the range 200–250 °C. Both reactions yield large amounts of polymer.It is postulated that the main reactions involve destruction of the reactant as it acts as a third body for recombination of nitrogen atoms. As the temperature is increased, dissociation of the nitrogen atom – reactant complex apparently increases. To account for the observed temperature effects, it is assumed that reactions also occur to regenerate reactant.Keywords
This publication has 3 references indexed in Scilit:
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- Perturbations and Predissociation in theBand SpectrumPhysical Review B, 1931
- THE NATURE OF ACTIVE NITROGEN: THE SYNTHESIS OF AMMONIA FROM THE ELEMENTS1Journal of the American Chemical Society, 1928