Transverse susceptibility in KH2PO4-type crystals

Abstract
A well-known model of ferroelectricity in potassium dihydrogen phosphate type crystals is extended to provide a description of observed transverse susceptibility in KH2PO4 and KH2AsPO4, the temperature dependence of which exhibits the expected antiferroelectric characteristics. Experimental data can be used in principle to determine the bond-bond interaction parameter J and the tunneling integral Γ. Available data provide satisfactory order-of-magnitude results, and are in qualitative agreement with determinations based on other experiments with regard to the relative values of Γ in two isomorphs. It is shown that more refined experimental data would contribute to a further understanding of this example of simultaneous ferroelectricity and antiferroelectricity in a single medium.

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