Rate and Mechanism of the Oxidative Addition of Phenyl Iodide to Pd0 Ligated by Triphenylarsine: Evidence for the Formation of a T-Shaped Complex [PhPdI(AsPh3)] and for the Decelerating Effect of CH2=CH−SnBu3 by Formation of [Pd0(η2-CH2=CH−SnBu3)(AsPh3)2]
- 10 May 2001
- journal article
- Published by Wiley in Chemistry – A European Journal
- Vol. 7 (10) , 2134-2142
- https://doi.org/10.1002/1521-3765(20010518)7:10<2134::aid-chem2134>3.0.co;2-9
Abstract
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This publication has 19 references indexed in Scilit:
- Role of dba in the reactivity of palladium(0) complexes generated in situ from mixtures of Pd(dba)2 and phosphinesCoordination Chemistry Reviews, 1998
- Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3 Catalyzed by trans-[PdR1IL2] (R1 = C6Cl2F3; R2 = Vinyl, 4-Methoxyphenyl; L = AsPh3)Journal of the American Chemical Society, 1998
- Comparative Reactivity of Palladium(0) Complexes Generated in Situ in Mixtures of Triphenylphosphine or Tri-2-furylphosphine and Pd(dba)2Organometallics, 1998
- Synthesis of Dumbbell-Shaped Organometallics: Synthesis of a Peralkynylated Dinuclear Cyclobutadiene ComplexOrganometallics, 1995
- Stille Coupling Reaction Using 4-(Trimethylsilyl)-2-butenylstannanes To Afford Allylic SilanesThe Journal of Organic Chemistry, 1995
- Synthesis of oxo-2-alkenylboronates and their cyclization to 3-methylene cycloalkanols via intramolecular allylborationJournal of the Chemical Society, Chemical Communications, 1994
- Rates and mechanisms of oxidative addition to zerovalent palladium complexes generated in situ from mixtures of Pd0(dba)2 and triphenylphosphineOrganometallics, 1993
- Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-couplingJournal of the Chemical Society, Chemical Communications, 1992
- Large rate accelerations in the stille reaction with tri-2-furylphosphine and triphenylarsine as palladium ligands: mechanistic and synthetic implicationsJournal of the American Chemical Society, 1991
- A novel palladium(0) complex; bis(dibenzylideneacetone)palladium(0)Journal of the Chemical Society D: Chemical Communications, 1970