Cyclic Sulfites and Cyclic Sulfates: Epoxide like Synthons
- 1 January 1992
- journal article
- review article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1992 (11) , 1035-1052
- https://doi.org/10.1055/s-1992-26295
Abstract
This article reviews the recent developing synthetic utilities of cyclic sulfites and cyclic sulfates in organic chemistry, which rival in reactivity and selectivity with their very well studied friend, the epoxides and in many cases, are found to be superior to them. 1. Introduction 2. Structure 3. Synthesis of Cyclic Sulfites 4. Synthesis of Cyclic Sulfates 5. Reactivity 5.1. Thermal Rearrangement 5.2. Photochemical Rearrangement 5.3. Reaction with Electrophiles 5.3.1.Reaction with Acids 5.3.2.Electrophilic Addition to Double Bonds 5.4. Reaction with Nucleophiles 5.4.1.O-Nucleophiles 5.4.2.S-Nucleophiles 5.4.3. Halide Nucleophiles 5.4.4.C-Nucleophiles 5.4.5. N-Nucleophiles 5.4.6. H-Nucleophiles 5.5. Reaction with Radicals 5.6. Electrochemical Reduction of Cyclic Sulfates 6. Application in Research and Industry 7. Biological Activities 8. ConclusionKeywords
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