Feldionen-Massenspektren organischer Moleküle IV. Olefine

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Abstract
The field ion mass spectra of the olefins are discussed. It is shown that the double bond and the bond next to it are very stable against field dissociation. The fragment patterns of all olefins show some features due to the stable configuration of the allyl radical or the allyl ion respectively. This is verified by some energetic calculations, by which the spectra of some olefins are explained, too. The stabilities of paraffins and olefins against field dissociation are compared.

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