An oxidative/reductive, non-hydrolytic procedure for ‘unravelling’ complex acetals (glycosides): a possible chemical role for the exo-anomeric effect
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1462-1464
- https://doi.org/10.1039/c39870001462
Abstract
A non-hydrolytic procedure has been developed for cleavage of complex acetals/glycosides in which one of the acetal oxygen atoms undergoes oxidative, bromine-induced addition to a remote olefinic centre, with formation of a tetrahydrofuran ring, which is subsequently cleaved reductively with zinc.Keywords
This publication has 0 references indexed in Scilit: