Enantioselective deacylation of long chain p-nitrophenyl N-acylphenyl-alanates by N-(N-dodecanoyl-L-histidyl)-L-leucine and a cationic chiral surfactant
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 637-639
- https://doi.org/10.1039/c39800000637
Abstract
Enhanced enantioselectivity (kcat L/kcat D 5·5–5·7) was observed in the deacylation of H[CH2]n– 1—CONHCH(CH2Ph)CO2C6H4NO2-p possessing long acyl chains (n 10–16) by comicelles of N-(N-dodecanoyl-L-histidyl)-L-leucine and (R)-(+)-N-α-methylbenzyl-NN-dimethyloctadecylammonium bromide.Keywords
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