Comparisons between experimental and calculated rate constants for dissociation and combination reactions involving small polyatomic molecules
- 1 November 1973
- journal article
- research article
- Published by Wiley in International Journal of Chemical Kinetics
- Vol. 5 (6) , 947-963
- https://doi.org/10.1002/kin.550050605
Abstract
The experimental results on decomposition and combination reactions involving O3, HNO3, NH3, C2N2, and NO2Cl over extended temperature and pressure ranges are compared with the deductions from RRKM calculations. Quantitative fits of the data over the entire range are possible only if the external (overall) rotations are assumed to be involved in the reactions. Recommended rate constants for the reactions O + O2+ N2→ O3+ N2and OH + NO2+ N2→ HNO3+ N2are presented.Keywords
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