Photoinduced reactions of PtCl62–with saturated hydrocarbons and other C–H containing compounds
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 671-672
- https://doi.org/10.1039/c39830000671
Abstract
Light irradiation of a solution of PtCl6 2– and an n-alkane (hexane or heptane) in MeCO2H or CF3CO2H–H2O yields the corresponding π-olefin complex of PtII, the formation of which is assumed to proceed via a σ-alkyl complex of PtIV; the reaction with acetone, which has no β-hydrogen atoms affords a stable σ-acetonyl complex of PtIV and σ-aryl complexes are formed on irradiation of PtCl6 2– with arenes.Keywords
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