Absolute configuration at the chiral nitrogen atom in an optically active oxaziridine. X-Ray structure of (2S)-(–)-N-(R)-α-methyl-benzyldiphenyloxaziridine
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 60-61
- https://doi.org/10.1039/c39760000060
Abstract
(R)-(–)-(Diphenylmethylene)-α-methylbenzyl-amine reacts with organic peroxy-acids in chloroform solution to give stereospecifically (2S)-(–)-N-(R)-α-methylbenzyldiphenyloxaziridine; X-ray crystal structure analysis shows that the absolute configuration at the configurationally stable chiral nitrogen atom is (S).Keywords
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